Abstract
The purpose of this paper is to highlight the design, development, and testing of a low-concentration vanadium redox flow battery (VRFB). The low-cost implementation has a 7 cm × 7 cm active membrane area and an electrolyte volume of 450 mL for each positive and negative electrolyte. The electrolyte concentration is approximately 0.066 M vanadium. An H-cell for performing electrolysis with the electrolytes is developed, and the process and method for creating the electrolyte for this low-concentration implementation are described and documented. The maximum power density and energy efficiency of the battery among tests between 500 and 800 mA are 1.32 W/L and 28.51%, respectively. Results are presented in terms of polarization curves, charge/discharge cycles, and voltage, coulombic, and energy efficiencies. Adaptation of a COMSOL Multiphysics model is implemented to compare the computational performance figures and the results of our VRFB implementation. The numerical results agree with experimentation, and differences in the results can be attributed to the losses present in the experimental tests. The proposed battery and design are intended to investigate the performance and feasibility of a low-concentration VRFB. The ultimate long-term objective of this research is the development of a novel, cost-effective, and safe redox flow battery using hydrogen peroxide as one of the electrolytes.
Issue Section:
Research Papers
References
1.
Ibrahim
, H.
, Ilinca
, A.
, and Perron
, J.
, 2008
, “Energy Storage Systems—Characteristics and Comparisons
,” Renew. Sustain. Energy Rev.
, 12
(5
), pp. 1221
–1250
. 10.1016/j.rser.2007.01.0232.
Miroshnikov
, M.
, Kato
, K.
, Babu
, G.
, Thangavel
, K. N.
, Mahankali
, K.
, Hohenstein
, E.
, Wang
, H.
, Satapathy
, S.
, Divya
, K. P.
, Asare
, H.
, Arava
, L. M. R.
, Ajayan
, P. M.
, and John
, G.
, 2019
, “Nature-Derived Sodium-Ion Battery: Mechanistic Insights Into Na-Ion Coordination Within Sustainable Molecular Cathode Materials
,” Am. Chem. Soc.
, 2
(12
), pp. 8596
–8604
. 10.1021/acsaem.9b015263.
Mahankali
, K.
, Thangavel
, K. N.
, Ding
, Y.
, Putatunda
, S. K.
, and Arava
, L. M. R.
, 2019
, “Interfacial Behavior of Water-in-Salt Electrolytes at Porous Electrodes and Its Effect on Supercapacitor Performance
,” Electrochim. Acta
, 326
, p. 134989
. 10.1016/j.electacta.2019.1349894.
Ponce de León
, C.
, Frías-Ferrer
, A.
, Gonzàlez-García
, J.
, Szánto
, D. A.
, and Walsh
, F.
, 2006
, “Redox Flow Cells for Energy Conversion
,” J. Power Sources
, 160
(1
), pp. 716
–732
. 10.1016/j.jpowsour.2006.02.0955.
Wang
, W.
, Luo
, Q.
, Li
, B.
, Wei
, X.
, Li
, L.
, and Yang
, Z.
, 2013
, “Recent Progress in Redox Flow Battery Research and Development
,” Adv. Funct. Mater.
, 23
(8
), pp. 970
–986
. 10.1002/adfm.2012006946.
Ledjeff
, K.
, and Reiner
, A.
, 1988
, “Iron/Chromium—Redox Battery: Battery Development for Photovoltaic Systems
,” Adv. Solar Energy Technol.
, 3
, pp. 2976
–2979
. 10.1016/B978-0-08-034315-0.50548-67.
Munaiah
, Y.
, Suresh
, S.
, Dheenadaylan
, S.
, Pillai
, V. K.
, and Ragupathy
, P.
, 2014
, “Comparative Electrocatalytic Performance of Single-Walled and Multiwalled Carbon Nanotubes for Zinc Bromine Redox Flow Batteries
,” J. Phys. Chem.
, 118
(27
), pp. 14795
–14804
. 10.1021/jp503287r8.
Munaiah
, Y.
, Dheenadaylan
, S.
, Ragupathy
, P.
, and Pillai
, V. K.
, 2013
, “High Performance Carbon Nanotube Based Electrodes for Zinc Bromine Redox Flow Batteries
,” ECS J. Solid State Sci. Technol.
, 2
(10
), pp. M3182
–M3186
. 10.1149/2.024310jss9.
Suresh
, S.
, Ulaganathan
, M.
, Venkatesan
, N.
, Periasamy
, P.
, and Ragupathy
, P.
, 2018
, “High Performance Zinc-Bromine Redox Flow Batteries: Role of Various Carbon Felts and Cell Configurations
,” J. Energy Storage
, 20
, pp. 134
–139
. 10.1016/j.est.2018.09.00610.
Rychcik
, M.
, and Skyllas-Kazacos
, M.
, 1988
, “Characteristics of a New All-Vanadium Redox Flow Battery
,” J. Power Sources
, 22
(1
), pp. 59
–67
. 10.1016/0378-7753(88)80005-311.
Li
, L.
, Kim
, S.
, Wang
, W.
, Vijayakumar
, M.
, Nie
, Z.
, Chen
, B.
, Zhang
, J.
, Xia
, G.
, Hu
, J.
, Graff
, G.
, Liu
, J.
, and Yang
, Z.
, 2011
, “A Stable Vanadium Redox-Flow Battery With High Energy Density for Large-Scale Energy Storage
,” Adv. Energy Mater.
, 1
(3
), pp. 394
–400
. 10.1002/aenm.20110000812.
Parasuraman
, A.
, Lim
, T. M.
, Menictas
, C.
, and Skyllas-Kazacos
, M.
, 2012
, “Review of Material Research and Development for Vanadium Redox Flow Battery Applications
,” Electrochim. Acta
, 101
, pp. 27
–40
. 10.1016/j.electacta.2012.09.06713.
Vafiadis
, H.
, and Skyllas-Kazacos
, M.
, 2006
, “Evaluation of Membranes for the Novel Vanadium Bromine Redox Flow Cell
,” J. Membr. Sci.
, 279
(1–2
), pp. 394
–402
. 10.1016/j.memsci.2005.12.02814.
Gundlapalli
, R.
, Kumar
, S.
, and Sreenivas
, J.
, 2018
, “Stack Design Considerations for Vanadium Redox Flow Battery
,” INAE Lett.
, 3
(3
), pp. 149
–157
. 10.1007/s41403-018-0044-115.
Li
, X.
, Zhang
, H.
, Mai
, Z.
, Zhanga
, H.
, and Vankelecom
, I.
, 2011
, “Ion Exchange Membranes for Vanadium Redox Flow Battery (VRB) Applications
,” Energy Environ. Sci.
, 4
(4
), pp. 1147
–1160
. 10.1039/c0ee00770f16.
Castañeda
, L. F.
, Walsh
, F. C.
, Nava
, J. L.
, and Ponce de León
, C.
, 2017
, “Graphite Felt as a Versatile Electrode Material: Properties, Reaction Environment, Performance and Applications
,” Electrochim. Acta
, 258
, pp. 1115
–1139
. 10.1016/j.electacta.2017.11.16517.
Aaron
, D.
, Liu
, Q.
, Tang
, Z.
, Grim
, G.
, Papandrew
, A.
, Turhan
, A.
, Zawodzinski
, T.
, and Mench
, M.
, 2012
, “Dramatic Performance Gains in Vanadium Redox Flow Batteries Through Modified Cell Architecture
,” J. Power Sources
, 206
, pp. 450
–453
. 10.1016/j.jpowsour.2011.12.02618.
Zhou
, X.
, Zhao
, T.
, Zeng
, Y.
, An
, L.
, and Wei
, L.
, 2016
, “A Highly Permeable and Enhanced Surface Area Carbon-Cloth Electrode for Vanadium Redox Flow Batteries
,” J. Power Sources
, 329
, pp. 247
–254
. 10.1016/j.jpowsour.2016.08.08519.
Skyllas-Kazacos
, M.
, 2003
, “Novel Vanadium Chloride/Polyhalide Redox Flow Battery
,” J. Power Sources
, 124
(1
), pp. 299
–302
. 10.1016/S0378-7753(03)00621-920.
Rahman
, F.
, and Skyllas-Kazacos
, M.
, 2009
, “Vanadium Redox Battery: Positive Half-Cell Electrolyte Studies
,” J. Power Sources
, 189
(2
), pp. 1212
–1219
. 10.1016/j.jpowsour.2008.12.11321.
Zhang
, J.
, Li
, L.
, Nie
, Z.
, Chen
, B.
, Vijayakumar
, M.
, Kim
, S.
, Wang
, W.
, Schwenzer
, B.
, Liu
, J.
, and Yang
, Z.
, 2011
, “Effects of Additives on the Stability of Electrolytes for All-Vanadium Redox Flow Batteries
,” J. Appl. Electrochem.
, 41
(10
), pp. 1215
–1221
. 10.1007/s10800-011-0312-122.
Wu
, X.
, Liu
, S.
, Wang
, N.
, Peng
, S.
, and He
, Z.
, 2012
, “Influence of Organic Additives on Electrochemical Properties of the Positive Electrolyte for All-Vanadium Redox Flow Battery
,” Electrochim. Acta
, 78
, pp. 475
–482
. 10.1016/j.electacta.2012.06.06523.
Chang
, F.
, Hu
, C.
, Liu
, X.
, Liu
, L.
, and Zhang
, J.
, 2012
, “Coulter Dispersant as Positive Electrolyte Additive for the Vanadium Redox Flow Battery
,” Electrochim. Acta
, 60
, pp. 334
–338
. 10.1016/j.electacta.2011.11.06524.
Wu
, X.
, Liu
, J.
, Xiang
, X.
, Zhang
, J.
, Hu
, J.
, and Wu
, Y.
, 2014
, “Electrolytes for Vanadium Redox Flow Batteries
,” Pure Appl. Chem.
, 86
(5
), pp. 661
–669
. 10.1515/pac-2013-121325.
Skyllas-Kazacos
, M.
, Kazacos
, G.
, Poon
, G.
, and Verseema
, H.
, 2010
, “Recent Advances With the UNSW Vanadium-Based Redox Flow Batteries
,” Int. J. Energy Res.
, 34
(2
), pp. 182
–189
. 10.1002/er.165826.
Park
, S.
, Lee
, H. J.
, Lee
, H.
, and Kim
, H.
, 2018
, “Development of a Redox Flow Battery With Multiple Redox Couples at Both Positive and Negative Electrolytes for High Energy Density
,” J. Electrochem. Soc.
, 165
(14
), pp. A3215
–A3220
. 10.1149/2.0301814jes27.
Menictas
, C.
, and Skyllas-Kazacos
, M.
, 2011
, “Performance of Vanadium-Oxygen Redox Fuel Cell
,” J. Appl. Electrochem.
, 41
(10
), pp. 1223
–1232
. 10.1007/s10800-011-0342-828.
An
, L.
, Zhao
, T.
, Zhou
, X.
, Yan
, X.
, and Jung
, C.
, 2015
, “A Low-Cost, High-Performance Zinc-Hydrogen Peroxide Fuel Cell
,” J. Power Sources
, 275
, pp. 831
–834
. 10.1016/j.jpowsour.2014.11.07629.
Xu
, T.
, 2005
, “Ion Exchange Membranes: State of Their Development and Perspective
,” J. Membr. Sci.
, 263
(1–2
), pp. 1
–29
. 10.1016/j.memsci.2005.05.00230.
Zhang
, H.
, Zhang
, H.
, Li
, X.
, Mai
, Z.
, and Zhang
, J.
, 2011
, “Nanofiltration (NF) Membranes: the Next Generation Separators for All Vanadium Redox Flow Batteries (VRBs)?
,” Energy Environ. Sci.
, 4
(5
), pp. 1676
–1679
. 10.1039/c1ee01117k31.
Sun
, B.
, and Skyllas-Kazacos
, M.
, 1992
, “Modification of Graphite Electrode Materials for Vanadium Redox Flow Battery Application—I. Thermal Treatment
,” Electrochim. Acta
, 37
(7
), pp. 1253
–1260
. 10.1016/0013-4686(92)85064-R32.
Pezeshki
, A. M.
, Clement
, J. T.
, Veith
, G. M.
, Zawodzinski
, T. A.
, and Mench
, M. M.
, 2015
, “High Performance Electrodes in Vanadium Redox Flow Batteries Through Oxygen-Enriched Thermal Activation
,” J. Power Sources
, 294
, pp. 333
–338
. 10.1016/j.jpowsour.2015.05.11833.
Eifert
, L.
, Banerjee
, R.
, Jusys
, Z.
, and Zeis
, R.
, 2018
, “Characterization of Carbon Felt Electrodes for Vanadium Redox Flow Batteries: Impact of Treatment Methods
,” J. Electrochem. Soc.
, 165
(11
), pp. A2577
–A2586
. 10.1149/2.0531811jes34.
González
, Z.
, Sánchez
, A.
, Blanco
, C.
, Granda
, M.
, Menéndez
, R.
, and Santamaría
, R.
, 2011
, “Enhanced Performance of a Bi-Modified Graphite Felt as the Positive Electrode of a Vanadium Redox Flow Battery
,” Electrochem. Commun.
, 13
(12
), pp. 1379
–1382
. 10.1016/j.elecom.2011.08.01735.
Wei
, L.
, Zhao
, T.
, Zhao
, G.
, An
, L.
, and Zeng
, L.
, 2016
, “A High-Performance Carbon Nanoparticle-Decorated Graphite Felt Electrode for Vanadium Redox Flow Batteries
,” Appl. Energy
, 176
, pp. 74
–79
. 10.1016/j.apenergy.2016.05.04836.
Yun
, N.
, Park
, J. J.
, Park
, O.
, Lee
, K. B.
, and Yang
, J. H.
, 2018
, “Electrocatalytic Effect of NiO Nanoparticles Evenly Distributed on Agraphite Felt Electrode for Vanadium Redox Flow Batteries
,” Electrochim. Acta
, 278
, pp. 226
–235
. 10.1016/j.electacta.2018.05.03937.
Flox
, C.
, Skoumal
, M.
, Rubio-Garcia
, J.
, Andreu
, T.
, and Morante
, J. R.
, 2013
, “Strategies for Enhancing Electrochemical Activity of Carbon-Based Electrodes for All-Vanadium Redox Flow Batteries
,” Appl. Energy
, 109
, pp. 344
–351
. 10.1016/j.apenergy.2013.02.00138.
Kim
, K. J.
, Kim
, Y.-J.
, Kim
, J.-H.
, and Park
, M.-S.
, 2011
, “The Effects of Surface Modification on Carbon Felt Electrodes for Use in Vanadium Redox Flow Batteries
,” Mater. Chem. Phys.
, 131
(1–2
), pp. 547
–553
. 10.1016/j.matchemphys.2011.10.02239.
Bhattarai
, A.
, Wai
, N.
, Schweiss
, R.
, Whitehead
, A.
, Lim
, T. M.
, and Hng
, H. H.
, 2017
, “Advanced Porous Electrodes With Flow Channels for Vanadium Redox Flow Battery
,” J. Power Sources
, 341
, pp. 83
–90
. 10.1016/j.jpowsour.2016.11.11340.
Li
, W.
, Liu
, J.
, and Yan
, C.
, 2011
, “Graphite–Graphite Oxide Composite Electrode for Vanadium Redox Flow Battery
,” Electrochim. Acta
, 56
(14
), pp. 5290
–5294
. 10.1016/j.electacta.2011.02.08341.
He
, Z.
, Li
, M.
, Li
, Y.
, Zhu
, J.
, Jiang
, Y.
, Meng
, W.
, Zhou
, H.
, Wang
, L.
, and Dai
, L.
, 2018
, “Flexible Electrospun Carbon Nanofiber Embedded With TiO2 as Excellent Negative Electrode for Vanadium Redox Flow Battery
,” Electrochim. Acta
, 281
, pp. 601
–610
. 10.1016/j.electacta.2018.06.01142.
Li
, W.
, Liu
, J.
, and Yan
, C.
, 2011
, “Multi-Walled Carbon Nanotubes Used as an Electrode Reaction Catalyst for VO2+/VO2+ for a Vanadium Redox Flow Battery
,” Carbon
, 49
(11
), pp. 3463
–3470
. 10.1016/j.carbon.2011.04.04543.
Wang
, Q.
, Qu
, Z.
, Jiang
, Z.
, and Yang
, W.
, 2018
, “Numerical Study on Vanadium Redox Flow Battery Performance With Non-Uniformly Compressed Electrode and Serpentine Flow Field
,” Appl. Energy
, 220
, pp. 106
–116
. 10.1016/j.apenergy.2018.03.05844.
Gurieff
, N.
, Timchenko
, V.
, and Menictas
, C.
, 2018
, “Variable Porous Electrode Compression for Redox Flow Battery Systems
,” Batteries
, 4
(4
), pp. 1
–10
. 10.3390/batteries404005345.
Darling
, R. M.
, and Perry
, M. L.
, 2014
, “The Influence of Electrode and Channel Configurations on Flow Battery Performance
,” J. Electrochem. Soc.
, 161
(9
), pp. A1381
–A1387
. 10.1149/2.0941409jes46.
Knudsen
, E.
, Albertus
, P.
, Cho
, K.
, Weber
, A.
, and Kojic
, A.
, 2015
, “Flow Simulation and Analysis of High-Power Flow Batteries
,” J. Power Sources
, 299
, pp. 617
–628
. 10.1016/j.jpowsour.2015.08.04147.
Xu
, Q.
, Zhao
, T.
, and Leung
, P.
, 2013
, “Numerical Investigations of Flow Field Designs for Vanadium Redox Flow Batteries
,” Appl. Energy
, 105
, pp. 47
–56
. 10.1016/j.apenergy.2012.12.04148.
Houser
, J.
, Clement
, J.
, Pezeshki
, A.
, and Mench
, M. M.
, 2016
, “Influence of Architecture and Material Properties on Vanadium Redox Flow Battery Performance
,” J. Power Sources
, 302
, pp. 369
–377
. 10.1016/j.jpowsour.2015.09.09549.
Messaggi
, M.
, Mereu
, R.
, Baricci
, A.
, Inzoli
, F.
, Casalegno
, A.
, and Zago
, M.
, 2018
, “Analysis of Flow Field Design on Vanadium Redox Flow Battery Performance: Development of 3D Computational Fluid Dynamic Model and Experimental Validation
,” Appl. Energy
, 228
, pp. 1057
–1070
. 10.1016/j.apenergy.2018.06.14850.
Tang
, A.
, Bao
, J.
, and Skyllas-Kazacos
, M.
, 2014
, “Studies on Pressure Losses and Flow Rate Optimization in Vanadium Redox Flow Battery
,” J. Power Sources
, 248
, pp. 154
–162
. 10.1016/j.jpowsour.2013.09.07151.
Lee
, N. J.
, Lee
, S.-W.
, Kim
, K. J.
, Kim
, J.-H.
, Park
, M.-S.
, Jeong
, G.
, Kim
, Y.-J.
, and Byun
, D.
, 2012
, “Development of Carbon Composite Bipolar Plates for Vanadium Redox Flow Batteries
,” Bull. Korean Chem. Soc.
, 33
(11
), pp. 3589
–3592
. 10.5012/bkcs.2012.33.11.358952.
Park
, M.
, Jung
, Y.-J.
, Ryu
, J.
, and Cho
, J.
, 2014
, “Material Selection and Optimization for Highly Stable Composite Bipolar Plates in Vanadium Redox Flow Batteries
,” J. Mater. Chem. A
, 2
(38
), pp. 15808
–15815
. 10.1039/C4TA03542A53.
Han
, J.
, Yoo
, H.
, Kim
, M.
, Lee
, G.
, and Choi
, J.
, 2017
, “High-Performane Bipolar Plate of Thin IrOx-Coated TiO2 Nanotubes in Vanadium Redox Flow Batteries
,” Catal. Today
, 295
, pp. 132
–139
. 10.1016/j.cattod.2017.06.01854.
Ma
, X.
, Zhang
, H.
, Sun
, C.
, Zou
, Y.
, and Zhang
, T.
, 2012
, “An Optimal Strategy of Electrolyte Flow Rate for Vanadium Redox Flow Battery
,” J. Power Sources
, 203
, pp. 153
–158
. 10.1016/j.jpowsour.2011.11.03655.
Cunha
, Á
, Martins
, J.
, Rodrigues
, N.
, and Brito
, F. P.
, 2014
, “Vanadium Redox Flow Batteries: A Technology Review
,” Int. J. Energy Res.
, 39
(7
), pp. 889
–918
. 10.1002/er.326056.
Skyllas-Kazacos
, M.
, Cao
, L.
, Kazacos
, M.
, Kausar
, N.
, and Mousa
, A.
, 2016
, “Vanadium Electrolyte Studeis for the Vanadium Redox Battery—A Review
,” ChemSusChem Rev.
, 9
(13
), pp. 1521
–1543
. 10.1002/cssc.20160010257.
Chanyong
, C.
, Kim
, S.
, Kim
, R.
, Choi
, Y.
, Kim
, S.
, Jung
, H. Y.
, Yang
, J. H.
, and Kim
, H. T.
, 2017
, “A Review of Vanadium Electrolytes for Vanadium Redox Flow Batteries
,” Renew. Sustain. Energy Rev.
, 69
, pp. 263
–274
. 10.1016/j.rser.2016.11.18858.
Knehr
, K. W.
, Agar
, E.
, Dennison
, C. R.
, Kalidindi
, A. R.
, and Kumbur
, E. C.
, 2012
, “A Transient Vanadium Flow Battery Model Incorporating Vanadium Crossover and Water Transport Through the Membrane
,” J. Electrochem. Soc.
, 159
(9
), pp. A1446
–A1459
. 10.1149/2.017209jes59.
Knehr
, K.
, and Kumbur
, E.
, 2011
, “Open Circuit Voltage of Vanadium Redox Flow Batteries: Discrepancy Between Models and Experiments
,” Electrochem. Commun.
, 13
(4
), pp. 342
–345
. 10.1016/j.elecom.2011.01.02060.
Shah
, A.
, Watt-Smith
, M.
, and Walsh
, F.
, 2008
, “A Dynamic Performance Model for Redox-Flow Batteries Involving Soluble Species
,” Electrochim. Acta
, 53
(27
), pp. 8087
–8100
. 10.1016/j.electacta.2008.05.067Copyright © 2020 by ASME
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