Abstract

This article presents a critical analysis of all the major pathways to produce hydrogen and to utilize it as an energy carrier to generate heat or electricity. The approach taken is to make a cradle to grave analysis including the production of hydrogen, the conversion of hydrogen to heat or electricity, and finally the utilization of that heat or electricity for a useful purpose. This methodology shows that no currently available hydrogen pathway, irrespective of whether it uses fossil fuels, nuclear fuels, or renewable technology as the primary energy source to generate electricity or heat is as efficient as using the electric power or heat from any of these sources directly. Furthermore, electric vehicles using batteries to store electricity are shown to be more efficient and less polluting than fuel cell powered vehicles using energy stored in hydrogen.

1.
Bush, G. W., United States State of the Union Message, 28 January 2003.
2.
National Vision of America’s Transition to a Hydrogen Economy in 2030 and Beyond, 2002, U.S. Dept. of Energy, Washington, DC.
3.
National Hydrogen Energy Road Map, 2002, U.S. Dept. of Energy, Washington, DC.
4.
The Hydrogen Economy: Opportunities, Costs, Barriers, and R&D Needs, 2003, Draft. National Research Council, National Academy of Engineering, The National Academies Press, Washington, DC; see www.nap.edu.
5.
Energy In Transition 1985–2010, 1979, National Research Council, National Academy of Sciences, Washington, DC.
6.
Schurr, S. H. et al., 1979, Energy in America’s Future—The Choices Before Us, Johns Hopkins University Press, Baltimore.
7.
Verne, J., 1988, The Mysterious Island, Antheneum, New York.
8.
Shinnar
,
R.
,
2003
, “
The Hydrogen Economy, Fuel Cells, and Electric Cars
,”
Tech. Soc.
,
25
(
4
), pp.
453
576
.
9.
Shinnar
,
R.
,
Shapira
,
D.
, and
Zakai
,
A.
,
1981
, “
Thermochemical and Hybrid Cycles for Hydrogen Production—A Differential Comparison with Electrolysis
,”
IEC Process Design Development
,
20
, p.
581
581
.
10.
Renewable Power Pathways—A Review of the U.S. Department of Energy’s Renewable Energy Programs, 2000, National Research Council, National Academies Press, Washington, DC.
11.
Kreith, F., and West, R. E., 2003, “Gauging Efficiency, Well to Wheel,” Mechanical Engineering Power 2003, supplement to Mechanical Engineering magazine.
12.
Kreith
,
F.
,
West
,
R. E.
, and
Isler
,
B. E.
,
2002
, “
Efficiency of Advanced Ground Transportation Technologies
,”
J. Energy Resour. Technol.
,
124
, pp.
173
179
.
13.
ASHRAE Handbook 1996, HVAC Systems and Equipment, 1996, American Society of Heating, Refrigeration and Air-Conditioning Engineers, Atlanta, GA.
1.
Steinfeld, A., in Renewable Hydrogen Forum, American Solar Energy Society, 1, October 2003, Middleton, P., Larson, R., Nicklas, M., and Collins, B., eds.
2.
See also, “Solar Hydrogen Production via a 2-step Water-Splitting Thermochemical Cycle based on Zn/ZnO Redox Reactions,” Int. J. Hydrogen Energy, 27, pp. 611–619.
1.
Perkins, C. and Weimer, A. W., “Likely Near-term Solar-Thermal Water Splitting Technologies,” Int. J. Hydrogen Energy (to be published).
2.
Howe-Grant, M., ed., 1995, Kirk-Othmer Encyclopedia of Chemical Technology, 4th Edition, Volume 13, Wiley, New York.
3.
Thomas
,
C. E.
,
Kuhn
, Jr.,
I. F.
,
James
,
B. D.
,
Lomas
, Jr.,
F. D.
, and
Baum
,
G. N.
,
1998
, “
Affordable Hydrogen Supply Pathways for Fuel Cell Vehicles
,”
Int. J. Hydrogen Energy
,
23
(
6
), pp.
507
516
.
4.
Stodolsky, F., Graines, L., Marshall, C. L., An, F., and Eberhardt, J. J., 1999, “Total Fuel Cycle Impacts of Advanced Vehicles,” Paper No. 199-01-0322, 1999 SAE International Congress and Exposition, Society of Automotive Engineers, Warrendale, PA.
5.
Penner, S. S., 2002, “Steps toward the Hydrogen Economy,” http://www.enviroliteracy.org.
6.
J. M., DeCicco, 2003, “The ‘Chicken or Egg’ Problem Writ Large: Why a Hydrogen Fuel Cell Focus is Premature,” Asilomar Conference on Transportation and Energy Policy, Asilomar, CA.
7.
Davis, S. C. and Diezel, S. W., 2002, Transportation Energy Data Book, 22 ed., Oak Ridge National Laboratory, Oak Ridge, TN.
8.
California Air Resources Board (CARB), Mobile Source Division. Staff Report, 1994 Low Emission Vehicle and Zero Emission Vehicle Program Review. Sacramento, CA.
9.
California Air Resources Board (CARB), ARB Modifies Zero Emission Vehicle Regulation. News Release, 2003, Sacramento, CA.
10.
Peseran, A., 1994, private communication. See also, Ito, I. K. and Ohnishi, M., 2003, “Development of Prismatic Type Nickel/Metal Hydride Battery for HEV,” Proceedings of the 20th International Electric Vehicle Symposium.
11.
McCoy, G. A. and Lyons, J. K., 1993, Electric Vehicles: An Alternative Fuels Vehicle. Emissions and Refueling Infrastructure Technology Assessment, Washington State Energy Office.
12.
Middleton, P., Larson, R., Nicklas, M., and Collins, B., eds., 2003, Renewable Hydrogen Forum, American Solar Energy Society.
13.
Lovins, A. B., “Twenty Hydrogen Myths,” Rocky Mountain Institute, 2003. See also Wold, M. L., New York Times, November 12, 1993, “Will Hydrogen Clean the Air? Maybe not, say some.”
14.
Kreith
,
F.
, and
Meyer
,
R. T.
,
1983
, “
Large Scale Use of Solar Energy with Central Receivers
,”
Am. Sci.
,
71
, pp.
598
605
.
15.
Barron, R. F., 2000, private communication.
16.
Timmerhaus, K. D. and Flynn, T. M., 1989, Cryogenic Process Engineering, Plenum, New York.
17.
Braun, H., in Renewable Hydrogen Forum, 2003, Middleton, P., Larson, R., Nicklas, M., and Collins, B., eds., American Solar Energy Society.
18.
Hydrogen Safety Information; Safetygrams for Gaseous and Liquid Hydrogen. www.airproducts.com/Products/LiquidBulkGases/or/Hydrogen Energy.
19.
Goel, N., Mirabal, S. T., Ingley, H. A., and Goswami, D. Y., 2003, “Hydrogen Production,” Chap. 11 in Advances in Solar Energy, Vol. 15, D. Y. Goswami, ed., American Solar Energy Society, Boulder, CO.
20.
Chemical Market Reporter, 2003, “Chemical Profile: Hydrogen.”
21.
McAlister, R. E., 2003, The Solar Hydrogen Civilization, American Hydrogen Association.
22.
Rifkin, J., 2002, The Hydrogen Economy: The Creation of the World-Wide Energy Web and the Redistribution of Power on Earth, Jeremy P. Tarcher.
23.
Dr. Joseph Romm. [March 3, 2004] Testimony for the hearing reviewing the Hydrogen Fuel and Freedom CAR Initiatives submitted to the house science committee Washington, DC.
You do not currently have access to this content.