The kinetic theory developed in [1] for solutions of nonhomogeneous nematic liquid crystalline polymers (LCPs) of spheroidal molecular configurations is extended to account for the translational diffusion and the related spatial density variation. The new theory augments the effect of the density variation to the intermolecular potential, Smoluchowski equation and the elastic stress. It accounts for the molecular aspect ratio as well as the finite range molecular interaction so that it is applicable to liquid crystals ranging from rodlike liquid crystals at large aspect ratios to discotic ones at small aspect ratios. It also exhibits enhanced shape effects in the viscous stress and warrants a positive entropy production, thereby, the second law of thermodynamics. Moment averaged, approximate, mesoscopic theories for complex flow simulations are obtained via closure approximations. In the limit of weak distortional elasticity, weak translational diffusion, and weak flows, the theory yields the torque balance equation of the well-known Ericksen-Leslie theory.
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March 2004
Technical Papers
A Kinetic Theory for Solutions of Nonhomogeneous Nematic Liquid Crystalline Polymers With Density Variations
Qi Wang,
Qi Wang
Department of Mathematics, Florida State University, Tallahassee, FL 32306-4510
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M. Gregory Forest,
M. Gregory Forest
Department of Mathematics, The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599
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Ruhai Zhou
Ruhai Zhou
Department of Mathematics, The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599
Search for other works by this author on:
Qi Wang
Department of Mathematics, Florida State University, Tallahassee, FL 32306-4510
M. Gregory Forest
Department of Mathematics, The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599
Ruhai Zhou
Department of Mathematics, The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599
Contributed by the Fluids Engineering Division for publication in the JOURNAL OF FLUIDS ENGINEERING. Manuscript received by the Fluids Engineering Division December 4, 2002; revised manuscript received August 28, 2003. Associate Editor: D. Siginer.
J. Fluids Eng. Mar 2004, 126(2): 180-188 (9 pages)
Published Online: May 3, 2004
Article history
Received:
December 4, 2002
Revised:
August 28, 2003
Online:
May 3, 2004
Citation
Wang, Q., Forest, M. G., and Zhou, R. (May 3, 2004). "A Kinetic Theory for Solutions of Nonhomogeneous Nematic Liquid Crystalline Polymers With Density Variations ." ASME. J. Fluids Eng. March 2004; 126(2): 180–188. https://doi.org/10.1115/1.1669031
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