The aim of this work is to investigate the performance of molten carbonate fuel cells (MCFCs), with external sensible heat reformer and gas turbine/steam turbine (GT/ST) combined cycles. The analysis of these MCFC-GT/ST combined cycles has been carried out using the thermo economic modular program (TEMP) modified to allow MCFC, external sensible heat reformer, and catalytic burner performance to be carefully taken into account. The code has been verified through the use of a detailed MCFC model and of the data available for an existing MCFC unit. The thermodynamic and exergy analysis of a number of MCFC combined cycles is presented and discussed, taking into account the influence of technological constraints, also evaluated with the sophisticated model, and the influence of the post-combustion of the fuel directly in the external catalytic burner. The results are presented and discussed in depth.

1.
Parodi, F., Alvarez, T., Bosio, B., Passalacqua, B., Simon, J., and Zappaterra, M., 1999, “Recent Achievements of MOLCARE Programme: Conditioning and Preliminary Testing of the 100 kW MCFC Stack,” 3rd IFCC, Nagoya Congress Center, Japan.
2.
Torazza, A., Rocchini, G., and Scagliotti, M., 1998, “Present Status of Some Technological Activities Supporting MOLCARE Project,” Proc. of Fuel Cell Seminar, Palm Spring, Orlando, FL, p. 390.
3.
Bosio
,
B.
,
Costamagna
,
P.
,
Parodi
,
F.
, and
Passalacqua
,
B.
,
1998
, “
Industrial Experience on the Development of the Molten Carbonate Fuel Cell Technology
,”
J. Power Sources
,
74
, No.
2
, pp.
175
187
.
4.
Bosio
,
B.
,
Costamagna
,
P.
, and
Parodi
,
F.
,
1999
, “
Modeling and Experimentation of Molten Carbonate Fuel Cell Reactors in a Scale-Up Process
,”
Chem. Eng. Sci.
54/13
, pp.
2913
2922
.
5.
Bedont, P., 1999, “Modellizzazione di celle a combustibile a carbonati fusi ed integrazione con impianti per la conversione di energia,” degree thesis, University of Genoa, Genoa, Italy.
6.
Agazzani
,
A.
, and
Massardo
,
A. F.
,
1997
, “
A Tool for Thermoeconomic Analysis and Optimization of Gas, Steam and Combined Plants
,”
ASME Trans. J. Eng. Gas Turbines Power
,
119
, pp.
885
892
.
7.
Massardo
,
A. F.
, and
Scialo
,
M.
,
2000
, “
Thermoeconomic Analysis of Gas Turbine Based Cycles
,”
ASME J. Eng. Gas Turbines Power
,
122
, pp.
27
35
.
8.
Bosio, B., Parodi, F., Arato, E., and Costamagna, P., 1999, “Process Analysis of a Molten Carbonate Fuel Cell Pilot Plan,” Proc. of ICheaP4 Conference, Firenze (Italy), pp. 651–654.
9.
Arato, E., Bosio, B., Massa, R., and Parodi, F., 1999, “From Square to Rectangular Cells in a MCFC Scale-Up Process: Experimental and Simulation Results Optimizing Operating Conditions,” Sixth Grove Fuel Cell Symposium, London.
10.
Wilson, D. G., and Korakianitis, T., 1997, The Design of High Efficiency Turbomachinery and Gas Turbines, Prentice-Hall, Englewood Cliffs, NJ.
11.
Massardo, A. F., 1999, “Gas Turbine Power Stations,” John Wiley Encyclopedia of Electronic and Electrical Engineering, J. Webster, Ed., Vol. 8, John Wiley and Sons, New York, pp. 258–270.
12.
Massardo
,
A. F.
, and
Lubelli
,
F.
,
2000
, “
Internal Reforming Solid Oxide Fuel Cell—Gas Turbine Combined Cycles (IRSOFC-GT). Part A: Cell Model and Cycle Thermodynamic Analysis
,”
ASME J. Eng. Gas Turbines Power
,
122
, pp.
664
671
.
13.
Massardo, A. F., and Magistri, L., 2001, “Internal Reforming Solid Oxide Fuel Cell—Gas Turbine Combined Cycles (IRSOFC-GT). Part B: Exergy and Thermoeconomic Analysis,” ASME Paper No. 01-GT-0380.
You do not currently have access to this content.