Three crucial aspects still to be overcome to achieve commercial competitiveness of the solar thermochemical production of hydrogen and carbon monoxide are recuperating the heat from the solid phase, achieving continuous or on-demand production beyond the hours of sunshine, and scaling to commercial plant sizes. To tackle all three aspects, we propose a moving brick receiver–reactor (MBR2) design with a solid–solid heat exchanger. The MBR2 consists of porous bricks that are reversibly mounted on a high temperature transport mechanism, a receiver–reactor where the bricks are reduced by passing through the concentrated solar radiation, a solid–solid heat exchanger under partial vacuum in which the reduced bricks transfer heat to the oxidized bricks, a first storage for the reduced bricks, an oxidation reactor, and a second storage for the oxidized bricks. The bricks may be made of any nonvolatile redox material suitable for a thermochemical two-step (TS) water splitting (WS) or carbon dioxide splitting (CDS) cycle. A first thermodynamic analysis shows that the MBR2 may be able to achieve solar-to-chemical conversion efficiencies of approximately 0.25. Additionally, we identify the desired operating conditions and show that the heat exchanger efficiency has to be higher than the fraction of recombination in order to increase the conversion efficiency.
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April 2019
Research-Article
Moving Brick Receiver–Reactor: A Solar Thermochemical Reactor and Process Design With a Solid–Solid Heat Exchanger and On-Demand Production of Hydrogen and/or Carbon Monoxide
Silvan Siegrist,
Silvan Siegrist
Institute of Solar Research,
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: Silvan.Siegrist@dlr.de
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: Silvan.Siegrist@dlr.de
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Henrik von Storch,
Henrik von Storch
Institute of Solar Research,
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: henrikstorch@rocketmail.com
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: henrikstorch@rocketmail.com
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Martin Roeb,
Martin Roeb
Institute of Solar Research,
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Martin.Roeb@dlr.de
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Martin.Roeb@dlr.de
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Christian Sattler
Christian Sattler
Institute of Solar Research,
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Christian.Sattler@dlr.de
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Christian.Sattler@dlr.de
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Silvan Siegrist
Institute of Solar Research,
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: Silvan.Siegrist@dlr.de
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: Silvan.Siegrist@dlr.de
Henrik von Storch
Institute of Solar Research,
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: henrikstorch@rocketmail.com
German Aerospace Center (DLR),
Professor-Rehm-Strasse 1,
Juelich 52428, Germany
e-mail: henrikstorch@rocketmail.com
Martin Roeb
Institute of Solar Research,
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Martin.Roeb@dlr.de
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Martin.Roeb@dlr.de
Christian Sattler
Institute of Solar Research,
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Christian.Sattler@dlr.de
German Aerospace Center (DLR),
Linder Hoehe,
Koeln 51147, Germany
e-mail: Christian.Sattler@dlr.de
1Corresponding author.
Contributed by the Solar Energy Division of ASME for publication in the JOURNAL OF SOLAR ENERGY ENGINEERING: INCLUDING WIND ENERGY AND BUILDING ENERGY CONSERVATION. Manuscript received September 7, 2018; final manuscript received November 18, 2018; published online January 8, 2019. Guest Editors: Tatsuya Kodama, Christian Sattler, Nathan Siegel, Ellen Stechel.
J. Sol. Energy Eng. Apr 2019, 141(2): 021009 (9 pages)
Published Online: January 8, 2019
Article history
Received:
September 7, 2018
Revised:
November 18, 2018
Citation
Siegrist, S., von Storch, H., Roeb, M., and Sattler, C. (January 8, 2019). "Moving Brick Receiver–Reactor: A Solar Thermochemical Reactor and Process Design With a Solid–Solid Heat Exchanger and On-Demand Production of Hydrogen and/or Carbon Monoxide." ASME. J. Sol. Energy Eng. April 2019; 141(2): 021009. https://doi.org/10.1115/1.4042069
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