For the first time, formation of cubic boron nitride (c-BN), besides Fe2B and iron nitrides, was detected in boronitride coating, which was applied via a duplex diffusional surface treatment. Boronitride coating was applied on AISI 1045 steel substrates via duplex treatment of pack boriding and plasma nitriding (B-PN). Scanning electron microscope (SEM), X-ray diffractometer (XRD), and pin-on-disk wear test were utilized to evaluate microstructures, phases, and wear properties of the coatings. The surface of the as-coated sample exhibited a pebblelike and compact structure, and the cross-sectional morphology of the coatings showed a saw-tooth interface with substrate. Duplex treated sample revealed superior wear resistance in comparison with the borided one.

References

1.
Doll
,
G. L.
,
1997
, “
Boron Nitride (BN) A2
,”
Handbook of Optical Constants of Solids
,
E. D.
Palik
, ed.,
Academic Press
,
Cambridge, MA
, pp.
425
443
.
2.
Termoss
,
H.
,
Toury
,
B.
,
Brioude
,
A.
,
Dazord
,
J.
,
Le Brusq
,
J.
, and
Miele
,
P.
,
2007
, “
High Purity Boron Nitride Thin Films Prepared by the PDCs Route
,”
Surf. Coat. Technol.
,
201
(
18
), pp.
7822
7828
.
3.
Madhav Reddy
,
K.
,
Hwang
,
C.
,
Ornek
,
M.
,
Miller
,
S. L.
,
Mayo
,
W. E.
,
Burgess
,
A.
,
Haber
,
R. A.
, and
Hemker
,
K. J.
,
2016
, “
Observations of Nanocrystalline Cubic Boron Nitride Formed With Plasma Spraying
,”
Acta Mater.
,
116
, pp.
155
165
.
4.
Vel
,
L.
,
Demazeau
,
G.
, and
Etourneau
,
J.
,
1991
, “
Cubic Boron Nitride: Synthesis, Physicochemical Properties and Applications
,”
Mater. Sci. Eng., B
,
10
(
2
), pp.
149
164
.
5.
Zhang
,
X. W.
,
2013
, “
Doping and Electrical Properties of Cubic Boron Nitride Thin Films: A Critical Review
,”
Thin Solid Films
,
544
, pp.
2
12
.
6.
Magielsen
,
A. J.
,
Bakker
,
K.
,
Chabrol
,
C.
,
Conrad
,
R.
,
van der Laan
,
J. G.
,
Rigal
,
E.
, and
Stijkel
,
M. P.
,
2002
, “
In-Pile Performance of a Double-Walled Tube and a Tritium Permeation Barrier
,”
J. Nucl. Mater.
,
307–311
(
Part 1
), pp.
832
836
.
7.
Ko
,
J. S.
,
Park
,
J. K.
,
Lee
,
W. S.
, and
Baik
,
Y. J.
,
2013
, “
The Parameter Space of Hydrogen Content Added to Ar–Nitrogen Sputtering Gas and Substrate Bias Voltage for the Formation of Cubic Boron Nitride Thin Film Deposited by Unbalanced Magnetron Sputtering Method
,”
Surf. Coat. Technol.
,
223
, pp.
75
78
.
8.
Li
,
J. S.
,
Zhang
,
C. R.
, and
Li
,
B.
,
2011
, “
Preparation and Characterization of Boron Nitride Coatings on Carbon Fibers From Borazine by Chemical Vapor Deposition
,”
Appl. Surf. Sci.
,
257
(
17
), pp.
7752
7757
.
9.
Liu
,
Y.
,
Chai
,
N.
,
Li
,
Z.
,
Ye
,
F.
,
Liu
,
X.
, and
Cheng
,
L.
,
2015
, “
Effect of Deposition Temperature on Deposition Kinetics and Mechanism of Silicon Boron Nitride Coating Deposited From SiCl4–BCl3–NH3–H2–Ar Mixture Using Low Pressure Chemical Vapor Deposition
,”
Surf. Coat. Technol.
,
261
, pp.
295
303
.
10.
Zheng
,
Y.
, and
Wang
,
S.
,
2011
, “
Synthesis of Boron Nitride Coatings on Quartz Fibers: Thickness Control and Mechanism Research
,”
Appl. Surf. Sci.
,
257
(
24
), pp.
10752
10757
.
11.
Teii
,
K.
, and
Matsumoto
,
S.
,
2015
, “
Impact of Low-Energy Ions on Plasma Deposition of Cubic Boron Nitride
,”
Thin Solid Films
,
576
, pp.
50
54
.
12.
Ulrich
,
S.
,
Ye
,
J.
,
Stüber
,
M.
, and
Ziebert
,
C.
,
2009
, “
Cubic Boron Nitride Based Metastable Coatings and Nanocomposites
,”
Thin Solid Films
,
518
(
5
), pp.
1443
1450
.
13.
Doñu Ruiz
,
M. A.
,
López Perrusquia
,
N.
,
Sánchez Huerta
,
D.
,
Torres San Miguel
,
C. R.
,
Urriolagoitia Calderón
,
G. M.
,
Cerillo Moreno
,
E. A.
, and
Cortes Suarez
,
J. V.
,
2015
, “
Growth Kinetics of Boride Coatings Formed at the Surface AISI M2 During Dehydrated Paste Pack Boriding
,”
Thin Solid Films
,
596
, pp.
147
154
.
14.
Campos
,
I.
,
Ramírez
,
G.
,
Figueroa
,
U.
,
Martínez
,
J.
, and
Morales
,
O.
,
2007
, “
Evaluation of Boron Mobility on the Phases FeB, Fe2B and Diffusion Zone in AISI 1045 and M2 Steels
,”
Appl. Surf. Sci.
,
253
(
7
), pp.
3469
3475
.
15.
Campos
,
I.
,
Farah
,
M.
,
López
,
N.
,
Bermúdez
,
G.
,
Rodríguez
,
G.
, and
VillaVelázquez
,
C.
,
2008
, “
Evaluation of the Tool Life and Fracture Toughness of Cutting Tools Boronized by the Paste Boriding Process
,”
Appl. Surf. Sci.
,
254
(
10
), pp.
2967
2974
.
16.
Samadi
,
V.
, and
Habibolahzadeh
,
A.
,
2010
, “
Evaluation of Microstructures and Wear Properties of Duplex Boride Coatings
,”
Mater. Sci. Technol.
,
26
(
1
), pp.
41
46
.
17.
Konyashin
,
I.
,
Loeffler
,
J.
,
Bill
,
J.
, and
Aldinger
,
F.
,
1997
, “
A Novel Approach to Deposition of Cubic Boron Nitride Coatings
,”
Thin Solid Films
,
308–309
, pp.
101
106
.
18.
Tamura
,
M.
,
Noma
,
M.
, and
Yamashita
,
M.
,
2014
, “
Characteristic Change of Hydrogen Permeation in Stainless Steel Plate by BN Coating
,”
Surf. Coat. Technol.
,
260
, pp.
148
154
.
19.
Wang
,
Y.
,
Lei
,
K.
,
Ruan
,
Y.
, and
Dong
,
W.
,
2016
, “
Microstructure and Wear Resistance of c-BN/Ni–Cr–Ti Composites Prepared by Spark Plasma Sintering
,”
Int. J. Refract. Met. Hard Mater.
,
54
, pp.
98
103
.
20.
Loeffler
,
J.
,
Konyashin
,
I.
,
Bill
,
J.
,
Uhlig
,
H.
, and
Aldinger
,
F.
,
1997
, “
PACVD Nano-Crystalline B C N Thin Films Obtained by Use of an Organoboron Precursor
,”
Diamond Relat. Mater.
,
6
(
5–7
), pp.
608
611
.
21.
Gómez-Vargas
,
O. A.
,
Solis-Romero
,
J.
,
Figueroa-López
,
U.
,
Ortiz-Domínguez
,
M.
,
Oseguera-Peña
,
J.
, and
Neville
,
A.
,
2016
, “
Boro-Nitriding Coating on Pure Iron by Powder-Pack Boriding and Nitriding Processes
,”
Mater. Lett.
,
176
, pp.
261
264
.
22.
Keddam
,
M.
,
Kulka
,
M.
,
Makuch
,
N.
,
Pertek
,
A.
, and
Małdziński
,
L.
,
2014
, “
A Kinetic Model for Estimating the Boron Activation Energies in the FeB and Fe2B Layers During the Gas-Boriding of Armco Iron: Effect of Boride Incubation Times
,”
Appl. Surf. Sci.
,
298
, pp.
155
163
.
23.
Haftlang
,
F.
,
Habibolahzadeh
,
A.
, and
Sohi
,
M. H.
,
2014
, “
Duplex Treatment of AISI 1045 Steel by Plasma Nitriding and Aluminizing
,”
Vacuum
,
107
, pp.
155
158
.
24.
Ashrafizadeh
,
F.
,
2003
, “
Influence of Plasma and Gas Nitriding on Fatigue Resistance of Plain Carbon (Ck45) Steel
,”
Surf. Coat. Technol.
,
174–175
, pp.
1196
1200
.
25.
Haftlang
,
F.
,
Habibolahzadeh
,
A.
, and
Sohi
,
M. H.
,
2015
, “
Improving Electrochemical Properties of AISI 1045 Steels by Duplex Surface Treatment of Plasma Nitriding and Aluminizing
,”
Appl. Surf. Sci.
,
329
, pp.
240
247
.
26.
Kumar
,
S. H.
,
Bhattacharyy
,
A.
,
Mondal
,
D. K.
,
Biswas
,
K.
, and
Maity
,
J.
,
2011
, “
Dry Sliding Wear Behaviour of Medium Carbon Steel Against an Alumina Disk
,”
Wear
,
270
(
5–6
), pp.
413
421
.
27.
Anasyida
,
A. S.
,
Daud
,
A. R.
, and
Ghazali
,
M.
,
2010
, “
Dry Sliding Wear Behaviour of Al–12Si–4Mg Alloy With Cerium Addition
,”
Mater. Des.
,
31
(
1
), pp.
365
374
.
28.
Kong
,
D.
, and
Zhao
,
B.
,
2017
, “
Effects of Loads on Friction–Wear Properties of HVOF Sprayed NiCrBSi Alloy Coatings by Laser Remelting
,”
J. Alloys Compd.
,
705
, pp.
700
707
.
29.
Tjong
,
S. C.
, and
Lau
,
K. C.
,
2000
, “
Dry Sliding Wear of TiB2 Particle Reinforced Aluminium Alloy Composites
,”
Mater. Sci. Technol.
,
16
(
1
), pp.
99
102
.
30.
Monteiro
,
S. N.
,
Skury
,
A. L. D.
,
de Azevedo
,
M. G.
, and
Bobrovnitchii
,
G. S.
,
2013
, “
Cubic Boron Nitride Competing With Diamond as a Superhard Engineering Material—An Overview
,”
J. Mater. Res. Technol.
,
2
(
1
), pp.
68
74
.
31.
Mashreghi
,
A. R.
,
Soleimani
,
S. M. Y.
, and
Saberifar
,
S.
,
2013
, “
The Investigation of Wear and Corrosion Behavior of Plasma Nitrided DIN 1.2210 Cold Work Tool Steel
,”
Mater. Des.
,
46
, pp.
532
538
.
32.
Joshi
,
A. A.
, and
Hosmani
,
S. S.
,
2014
, “
Pack-Boronizing of AISI 4140 Steel: Boronizing Mechanism and the Role of Container Design
,”
Mater. Manuf. Processes
,
29
(
9
), pp.
1062
1072
.
33.
Selçuk
,
B.
,
Ipek
,
R.
, and
Karamış
,
M. B.
,
2003
, “
A Study on Friction and Wear Behaviour of Carburized, Carbonitrided and Borided AISI 1020 and 5115 Steels
,”
J. Mater. Process. Technol.
,
141
(
2
), pp.
189
196
.
34.
Luo
,
X. T.
, and
Li
,
C. J.
,
2015
, “
Large Sized Cubic BN Reinforced Nanocomposite With Improved Abrasive Wear Resistance Deposited by Cold Spray
,”
Mater. Des.
,
83
, pp.
249
256
.
35.
Stachowiak
,
G. W.
, and
Batchelor
,
A. W.
,
2006
, “
Chapter 14—Fatigue Wear
,”
Engineering Tribology
, 3rd ed.,
Butterworth-Heinemann
,
Oxford, UK
, pp.
595
619
.
You do not currently have access to this content.